Oxiranes are a class of cyclic ethers formed in abundance during low‐temperature
combustion of hydrocarbons and biofuels, either via chain‐propagating steps that occur from …

Degenerate chain-branching mechanisms of n-alkanes are centered on the formation of
hydroperoxy-alkyl radicals (̇QOOH), formed via ̇R + O 2 reactions, and the ensuing …

Multiplexed photoionization mass spectrometry (MPIMS) is utilized to examine reaction
mechanisms of ̇QOOH radicals derived from cyclohexene, a primary intermediate in low-…

Absorption cross-sections were measured in the vacuum ultraviolet from 5.17 – 9.92 eV
using differential absorption spectroscopy for 33 four-carbon species: n-butane, trans-2-butene, …

Abstract Machine learning methods were combined with differential absorption spectroscopy
measurements in the vacuum-ultraviolet region (5.167 – 9.920 eV) in order to develop …

Low-temperature combustion is a promising strategy for reducing pollutant formation in
internal combustion engines. However, there is a lack of understanding of how the chemistry …

Oxiranes are a class of cyclic ethers formed in abundance during low‐temperature
combustion of hydrocarbons and biofuels, either via chain‐propagating steps that occur from …

Photolytically initiated oxidation experiments were conducted on cyclohexane and
tetrahydropyran using multiplexed photoionization mass spectrometry to assess the impact of the …

Low-temperature oxidation of tetrahydrofuran involves competing reactions that depend on
temperature, pressure, and oxygen concentration, including ring-opening and subsequent …

Cross-sections were measured at 50 C and 800 Torr using differential absorption
spectroscopy in the vacuum-ultraviolet from 5.17 – 9.92 eV for a series of five-membered cyclic …