Skip to main content
SpringerLink
Log in

Coordination complexes of iron(III) with 3-hydroxy-2(1H)-pyridinone, 2,3-dihydroxybenzoic acid and 3,4-dihydroxybenzoic acid: preparation and characterization in the solid state

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The synthesis and study of a number of new iron(III) complexes of the ligands 3-hydroxy-2(1H)-pyridinone (3,2-opoH), 2,3-dihydroxybenzoic acid (2,3-dhbH3) and 3,4-dihydroxybenzoic acid (3,4-dhbH3) are described. These complexes have the formulae [Fe(3,2-opo)2Cl]·PrnOH, K[Fe(2,3-dhbH)2(H2O)2], [Fe(2,3-dhb)(H2O)2], K[Fe-(3,4-dhbH)2(H2O)2], [Fe(3,4-dhb)(H2O)2] and K6[Fe(3,4-dhb)3]·3H2O. The complexes were characterized by elemental analyses. X-ray powder patterns, t.g.a./d.t.g. techniques, magnetic susceptibilities and spectroscopic (u.v.-vis., i.r. and variable-temperature 57Fe-Mössbauer) studies. Monomeric octahedral structures are assigned for the 1∶2 2,3-dhbH2− complex and the 1:3 3,4-dhb3− compound. Dinuclear and/or oligonuclear structures are tentatively proposed for the remaining complexes in the solid state. In [FeL(H2O)2] (L3− = 2,3-dhb3− or 3,4-dhb3−), iron(III) appears to be 5-coordinate. Both oxygens of 3,2-opo− participate in coordination, while the dihydroxybenzoato ligands exhibit various coordination modes, depending mainly on the positions of the hydroxy groups, their anionic charge and the ligand∶metal molar ratio used.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. C. Scarrow and K. N. Raymond, Inorg. Chem., 27, 4140 (1988) and references therein.

    Article  CAS  Google Scholar 

  2. W. Kiggen and F. Vogtle, Angew. Chem. Int. Ed. Engl., 23, 714 (1984).

    Article  Google Scholar 

  3. A. E. Martell, W. F. Anderson and D. G. Badman (Eds), Development of Iron Chelators for Clinical Use, Elsevier/North Holland, Amsterdam, 1981.

    Google Scholar 

  4. J. B. Neilands, Annu. Rev. Microbiol., 36, 285 (1982).

    Article  CAS  Google Scholar 

  5. M. E. Cass, T. M. Garrett and K. N. Raymond, J. Am. Chem. Soc., 111, 1677 (1989) and references therein.

    Article  CAS  Google Scholar 

  6. R. C. Hider, D. Bickar, I. E. G. Morrison and J. Silver, J. Am. Chem. Soc., 106, 6983 (1984) and references therein.

    Article  CAS  Google Scholar 

  7. G. J. Kontoghiorghes, Inorg. Chim. Acta, 135, 145 (1987).

    Article  CAS  Google Scholar 

  8. G. Xiao, D. van der Helm, R. C. Hider and P. S. Dobbin, J. Chem. Soc., Dalton Trans., 3265 (1992) and references therein.

  9. G. E. Freeman and K. N. Raymond, Inorg. Chem., 24, 1410 (1985).

    Article  CAS  Google Scholar 

  10. R. C. Scarrow, D. L. White and K. N. Raymond, J. Am. Chem. Soc., 107, 6540 (1985) and references therein.

    Article  CAS  Google Scholar 

  11. D. M. Taylor and G. J. Kontoghiorghes, Inorg. Chim. Acta, 125, L35 (1986).

    Article  CAS  Google Scholar 

  12. S. M. Moerlein, M. J. Welch and K. N. Raymond, J. Nucl. Med., 23, 501 (1982).

    CAS  Google Scholar 

  13. R. Fossheim, H. Dugstad and S. G. Dahl, J. Med. Chem., 34, 819 (1991) and references therein.

    Article  CAS  Google Scholar 

  14. T. Glowiak, H. Kozlowski, L. S. Erre, G. Micera and B. Gulinati, Inorg. Chim. Acta, 202, 43 (1992) and references therein.

    Article  CAS  Google Scholar 

  15. L. S. Erre, G. Micera, B. Gulinati and F. Cariati, Polyhedron, 11, 101 (1992) and references therein.

    Article  CAS  Google Scholar 

  16. L. S. Erre, G. Micera, F. Cariati, G. Ciani, A. Sironi, H. Boslowski and J. Karanowski, J. Chem. Soc., Dalton Trans., 363 (1988).

  17. O. Carugo, C. B. Castellani, K. Djinovic and M. Rizzi, J. Chem. Soc., Dalton Trans., 837 (1992).

  18. A. Ozarowski, B. R. McGarvey, C. Peppe and D. G. Tuck, J. Am. Chem. Soc., 113, 3288 (1991).

    Article  CAS  Google Scholar 

  19. H. Masui, A. B. P. Lever and P. R. Auburn, Inorg. Chem., 30, 2402 (1991).

    Article  CAS  Google Scholar 

  20. D. Zirong, S. Bhattacharya, J. K. McCusker, P. M. Hagen, D. N. Hendrickson and C. G. Pierpont, Inorg. Chem., 31, 870 (1992) and references therein.

    Article  Google Scholar 

  21. J. Xu and R. B. Jordan, Inorg. Chem., 27, 1502 (1988).

    Article  CAS  Google Scholar 

  22. L. Cun and R. B. Jordan, Inorg. Chem., 29, 2937 (1990).

    Article  CAS  Google Scholar 

  23. M. Aplincourt, C. Gerard, R. P. Hugel, J. C. Pierrard, J. Rimbault, A. Bertrandie, B. Magny and R. J. Siret, Polyhedron, 11, 1161 (1992).

    Article  CAS  Google Scholar 

  24. W. O. Nelson, T. B. Karpishin, S. J. Rettig and C. Orvig, Inorg. Chem., 27, 1045 (1988).

    Article  CAS  Google Scholar 

  25. D. F. Evans, J. Parr and C. Y. Wong, Polyhedron, 11, 567 (1992).

    Article  CAS  Google Scholar 

  26. W. P. Griffith and S. I. Mostafa, Polyhedron, 11, 2997 (1992).

    Article  CAS  Google Scholar 

  27. C. I. F. Denekamp, D. F. Evans, A. M. Z. Slawin, D. J. Williams, C. Y. Wong and J. D. Woolins, J. Chem. Soc., Dalton Trans., 2375 (1992).

  28. K. E. Curtis and G. F. Atkinson, Can. J. Chem., 50, 1649 (1972).

    Article  CAS  Google Scholar 

  29. E. Mentasti, E. Pelizzetti and C. Baiocchi, Annali di Chimica, 66, 401 (1976).

    CAS  Google Scholar 

  30. B. Howlin, R. C. Hider and J. Silver, J. Chem. Soc., Dalton Trans., 1433 (1982).

  31. R. C. Scarrow, P. E. Riley, K. Abu-Dari, D. L. White and K. N. Raymond, Inorg. Chem., 24, 954 (1985).

    Article  CAS  Google Scholar 

  32. A. Avdeef, S. R. Sofen, T. L. Bregante and K. N. Raymond, J. Am. Chem. Soc., 100, 5362 (1978).

    Article  CAS  Google Scholar 

  33. R. C. Hider, A. R. Mohd-Nor, J. Silver, I. E. G. Morrison and L. V. C. Rees, J. Chem. Soc., Dalton Trans., 609 (1981).

  34. M. Louloudi and N. Hadjiliadis, J. Chem. Soc., Dalton Trans., 1635 (1991).

  35. F. J. Quaeyhaegens, H. O. Desseyn, S. P. Perlepes, J. C. Plakatouras, B. Bracke and A. T. H. Lenstra, Transition Met. Chem., 16, 92 (1991).

    Article  CAS  Google Scholar 

  36. M. Louloudi, N. Hadjiliadis, J.-A. Feng, S. Sukumar and R. Bau, J. Am. Chem. Soc., 112, 7233 (1990).

    Article  CAS  Google Scholar 

  37. For the designation of “pH” in a nonaqueous medium see V. L. Pecoraro, G. B. Wong, T. A. Kent and K. N. Raymond, J. Am. Chem. Soc., 105, 4617 (1983).

    Article  CAS  Google Scholar 

  38. K. Gerega, H. Kozlowski, T. Kiss, G. Micera, L. S. Erre and F. Cariati, Inorg. Chim. Acta, 138, 31 (1987).

    Article  CAS  Google Scholar 

  39. T. Kiss, H. Kozlowski, G. Micera and L. S. Erre, J. Coord. Chem., 20, 49 (1989).

    Article  CAS  Google Scholar 

  40. J. T. Wrobleski and D. B. Brown, Inorg. Chem., 18, 2738 (1979).

    Article  CAS  Google Scholar 

  41. B. P. Murch, F. C. Bradley, P. D. Boyle, V. Papaefthymiou and L. Que Jr, J. Am. Chem. Soc., 109, 7993 (1987).

    Article  CAS  Google Scholar 

  42. J. E. Plowman, T. M. Loehr, C. K. Schauer and O. P. Anderson, Inorg. Chem., 23, 3553 (1984) and references therein.

    Article  CAS  Google Scholar 

  43. N. N. Greenwood and T. C. Gibb, Mössbauer Spectroscopy, Chapman & Hall, London, 1971, Chap. 6.

    Google Scholar 

  44. M. W. Lynch, M. Valentine and D. N. Hendrickson, J. Am. Chem. Soc., 104, 6982 (1982).

    Article  CAS  Google Scholar 

  45. W. B. Tolman, S. Liu, J. G. Bentsen and S. J. Lippard, J. Am. Chem. Soc., 113, 152 (1991).

    Article  CAS  Google Scholar 

  46. D. M. Kurtz Jr, Chem. Rev., 90, 585 (1990).

    Article  CAS  Google Scholar 

  47. K. L. Taft and S. J. Lippard, J. Am. Chem. Soc., 112, 9629 (1990).

    Article  CAS  Google Scholar 

  48. S. R. Boone, G. H. Purser, H.-R. Chang, M. D. Lowery, D. N. Hendrickson and C. G. Pierpont, J. Am. Chem. Soc., 111, 2292 (1989).

    Article  CAS  Google Scholar 

  49. V. L. Pecoraro, W. R. Harris, G. B. Wong, C. J. Karrano and K. N. Raymond, J. Am. Chem. Soc., 105, 4623 (1983).

    Article  CAS  Google Scholar 

  50. F. Cariati, L. Erre, G. Micera, A. Panzanelli, G. Ciani and A. Sironi, Inorg. Chim. Acta, 80, 57 (1983).

    Article  CAS  Google Scholar 

  51. E. Spinner and J. C. B. White, J. Chem. Soc. (B), 991 (1966).

  52. J. G. Vos, Inorg. Chim. Acta, 99, 117 (1985).

    Article  CAS  Google Scholar 

  53. L. S. Gelfand, F. J. Iaconianni, L. L. Pytlewski, A. N. Speca, C. M. Mikulski and N. M. Karayannis, J. Inorg. Nucl. Chem., 42, 377 (1980).

    Article  CAS  Google Scholar 

  54. S. P. Perlepes, F. J. Quaeyhaegens and H. O. Desseyn, Transition Met. Chem., 15, 132 (1990).

    Article  CAS  Google Scholar 

  55. G. B. Deacon and R. J. Phillips, Coord. Chem. Rev., 33, 227 (1980).

    Article  CAS  Google Scholar 

  56. S. Salama, J. D. Strong, J. B. Neilands and T. G. Spiro, Biochemistry, 17, 3781 (1978).

    Article  CAS  Google Scholar 

  57. L. Que Jr, and R. H. Heistand, J. Am. Chem. Soc., 101, 2219 (1979).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Inorganic Chemistry, Department of Chemistry, University of Athens, 15701, Panepistimiopolis, Kouponia, Greece

    Maria Kamariotaki, Alexandra Karaliota & Despina Stabaki

  2. Department of Physics, University of Ioannina, 451 10, Ioannina, Greece

    Thomas Bakas

  3. Department of Chemistry, University of Patras, Patra, Greece

    Spyros P. Perlepes

  4. Laboratory of General and Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10, Ioannina, Greece

    Nick Hadjiliadis

Authors
  1. Maria Kamariotaki
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Alexandra Karaliota
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Despina Stabaki
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Thomas Bakas
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Spyros P. Perlepes
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Nick Hadjiliadis
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kamariotaki, M., Karaliota, A., Stabaki, D. et al. Coordination complexes of iron(III) with 3-hydroxy-2(1H)-pyridinone, 2,3-dihydroxybenzoic acid and 3,4-dihydroxybenzoic acid: preparation and characterization in the solid state. Transition Met Chem 19, 241–247 (1994). https://doi.org/10.1007/BF00161899

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00161899

Keywords

Search

Navigation