Scaling Analysis of Dynamic Heterogeneity in a Supercooled Lennard-Jones Liquid

Richard S. L. Stein and Hans C. Andersen
Phys. Rev. Lett. 101, 267802 – Published 30 December 2008

Abstract

We have performed molecular dynamics computer simulations of a dense Lennard-Jones liquid mixture to study dynamic heterogeneity from normal liquid temperatures down to a supercooled temperature 15% above the previously identified mode-coupling temperature Tc of the model. A temperature-dependent correlation length associated with the correlation function of mobility fluctuations is calculated. The results are used to test two sets of scaling hypotheses for the dynamic heterogeneity. The results are in close agreement with the inhomogeneous mode-coupling theory of Biroli et al. [Phys. Rev. Lett. 97, 195701 (2006)] for both the α and β relaxation regimes. Comparison with results for kinetically constrained models suggest that the Lennard-Jones mixture studied is more similar to models of fragile liquids than models of very strong liquids.

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  • Received 17 April 2007

DOI:https://doi.org/10.1103/PhysRevLett.101.267802

©2008 American Physical Society

Authors & Affiliations

Richard S. L. Stein* and Hans C. Andersen

  • Department of Chemistry, Stanford University, Stanford, California 94305, USA

  • *Present address: Department of Chemistry and Biochemistry, UC San Diego, La Jolla, CA 92093. rstein@ucsd.edu.

Comments & Replies

Comment on “Scaling Analysis of Dynamic Heterogeneity in a Supercooled Lennard-Jones Liquid”

Smarajit Karmakar, Chandan Dasgupta, and Srikanth Sastry
Phys. Rev. Lett. 105, 019801 (2010)

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Vol. 101, Iss. 26 — 31 December 2008

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