Abstract
We have performed molecular dynamics computer simulations of a dense Lennard-Jones liquid mixture to study dynamic heterogeneity from normal liquid temperatures down to a supercooled temperature 15% above the previously identified mode-coupling temperature of the model. A temperature-dependent correlation length associated with the correlation function of mobility fluctuations is calculated. The results are used to test two sets of scaling hypotheses for the dynamic heterogeneity. The results are in close agreement with the inhomogeneous mode-coupling theory of Biroli et al. [Phys. Rev. Lett. 97, 195701 (2006)] for both the and relaxation regimes. Comparison with results for kinetically constrained models suggest that the Lennard-Jones mixture studied is more similar to models of fragile liquids than models of very strong liquids.
- Received 17 April 2007
DOI:https://doi.org/10.1103/PhysRevLett.101.267802
©2008 American Physical Society