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C-C bond forming radical SAM enzymes involved in the construction of carbon skeletons of cofactors and natural products.
Nat Prod Rep. 2018 Jul 18;35(7):660-694. doi: 10.1039/c8np00006a.
Nat Prod Rep. 2018.
PMID: 29633774
Free PMC article.
Review.
Carbon extension in peptidylnucleoside biosynthesis by radical SAM enzymes.
Lilla EA, Yokoyama K.
Lilla EA, et al.
Nat Chem Biol. 2016 Nov;12(11):905-907. doi: 10.1038/nchembio.2187. Epub 2016 Sep 19.
Nat Chem Biol. 2016.
PMID: 27642865
Free PMC article.
Item in Clipboard
Mechanism of Rate Acceleration of Radical C-C Bond Formation Reaction by a Radical SAM GTP 3',8-Cyclase.
Pang H, Lilla EA, Zhang P, Zhang D, Shields TP, Scott LG, Yang W, Yokoyama K.
Pang H, et al. Among authors: lilla ea.
J Am Chem Soc. 2020 May 20;142(20):9314-9326. doi: 10.1021/jacs.0c01200. Epub 2020 May 11.
J Am Chem Soc. 2020.
PMID: 32348669
Free PMC article.
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Paradigm Shift for Radical S-Adenosyl-l-methionine Reactions: The Organometallic Intermediate Ω Is Central to Catalysis.
Byer AS, Yang H, McDaniel EC, Kathiresan V, Impano S, Pagnier A, Watts H, Denler C, Vagstad AL, Piel J, Duschene KS, Shepard EM, Shields TP, Scott LG, Lilla EA, Yokoyama K, Broderick WE, Hoffman BM, Broderick JB.
Byer AS, et al. Among authors: lilla ea.
J Am Chem Soc. 2018 Jul 18;140(28):8634-8638. doi: 10.1021/jacs.8b04061. Epub 2018 Jul 6.
J Am Chem Soc. 2018.
PMID: 29954180
Free PMC article.
Item in Clipboard
Mechanistic Investigation of cPMP Synthase in Molybdenum Cofactor Biosynthesis Using an Uncleavable Substrate Analogue.
Hover BM, Lilla EA, Yokoyama K.
Hover BM, et al. Among authors: lilla ea.
Biochemistry. 2015 Dec 15;54(49):7229-36. doi: 10.1021/acs.biochem.5b00857. Epub 2015 Dec 1.
Biochemistry. 2015.
PMID: 26575208
Free PMC article.
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