Carbon dioxide electroreduction facilitates the sustainable synthesis of fuels and chemicals
1 . Although Cu enables CO 2 -to-multicarbon product (C 2+ ) conversion, the nature of the …

X-ray crystallography at X-ray free-electron laser sources is a powerful method for studying
macromolecules at biologically relevant temperatures. Moreover, when combined with …

The mainline feature in metal Kβ X-ray emission spectroscopy (XES) has long been recognized
as an experimental marker for the spin state of the metal center. However, even within a …

The sensitivity of iron Kβ X-ray emission spectroscopy (XES) to the nature of the bound
ligands (σ-donating, π-donating, and π-accepting) has been explored. A combination of …

Advances in electrocatalysis research rely heavily on building a thorough mechanistic
understanding of catalyst active sites under realistic operating conditions. Only recently have …

Conspectus A long-standing goal of inorganic chemists is the ability to decipher the geometric
and electronic structures of chemical species. This is particularly true for the study of small …

Pulsing the potential during the electrochemical CO 2 reduction (CO 2 R) reaction using copper
has been shown to influence product selectivity (ie, to suppress the undesired hydrogen …

Iron(II)- and 2-(oxo)-glutarate-dependent oxygenases catalyze diverse oxidative transformations
that are often initiated by abstraction of hydrogen from carbon by iron(IV)-oxo (ferryl) …

The Cerrado biome covers a large area of central Brazil, containing a mosaic of physiognomies
determined by soil fertility, seasonal rainfall, and fire. The ground layer vegetation …

Animals often show reduced reproductive success in urban compared to adjacent natural
areas. The lower availability and quality of natural food in cities is suggested as one key …