Despite advances in the scope of palladium-catalyzed CÀN bond-forming reactions through
the development of more active catalysts,[1, 2] limitations to the method still remain: 1) In …

4,7-Dimethoxy-1,10-phenanthroline (L1c) was found to be an efficient ligand for the copper-catalyzed
N-arylation of imidazoles and benzimidazoles with both aryl iodides and bromides …

4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed
N-arylation of imidazole with aryl iodides and bromides under mild conditions. A …

The use of 3,4,7,8-tetramethyl-1,10-phenanthroline (Me 4 Phen) as a ligand improves the
Cu-catalyzed cross-coupling reactions of aryl iodides and bromides with primary and …

The enantioselective α-arylation and α-vinylation of oxindoles catalyzed by Pd and a
biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The …

In the cross-coupling reactions of unprotected oxindoles with aryl halides, Pd- and Cu-based
catalyst systems displayed orthogonal chemoselectivity. A Pd-dialkylbiarylphosphine-…

gem‐Difluorinated alkenes are readily accessible building blocks that can undergo functionalization
to provide a broad spectrum of fluorinated and non‐fluorinated products. Herein, we …

With use of Cu-based catalysts, 2- and 4-hydroxypyridines were N-arylated in modest to
excellent yields. In the case of 2-hydroxypyridine, the use of 4,7-dimethoxy-1,10-phenanthroline, …

The following protocol describes the application of a highly active Pd-based catalyst system
in the Suzuki–Miyaura cross-coupling reaction of arylboronic acids with aryl chlorides to …

α,α‐Difluoroketones possess unique physicochemical properties that are useful for
developing therapeutics and probes for chemical biology. To access the α‐allyl‐α,α‐difluoroketone …